Crystalline Molecular Complexes and Compounds: Structures and Principles, Band 2Oxford University Press, 2005 - 1273 Seiten This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous example but others (hydrates, solvates, host-guest inclusion complexes, donor-acceptor compounds) pervade the whole body of solid state chemistry. Although much research has been published, there has never been a comprehensive and unified treatment of the whole field. This book has been designed to fill this gap, comparing and contrasting the various examples and the different types of interaction (hydrogen bonding, inclusion and localized or delocalized charge transfer). More than 600 figures, 200 tables and 3500 references are included in the book. Since most 'parent compounds' form a number of adducts, the fraction of crystalline binary adducts is only going to grow making this account just the 'tip of the iceberg.' |
Inhalt
Introduction to Part V | 681 |
Pure acceptors | 687 |
PACKING COMPLEXES | 704 |
methanes as acceptors | 731 |
Selfinteracting acceptors | 737 |
Hydrogen bonded molecular complexes and compounds | 788 |
Volume 1 | 845 |
Cyclodextrins and some analogs as hosts | 852 |
Crystal chemistry of mixedstack лл molecular compounds | 989 |
compounds | 1007 |
bonding interactions | 1026 |
Crystal structural physics of mixed stack лл | 1081 |
90 | 1138 |
Segregated stack лmolecular complexes | 1147 |
114 | 1171 |
117 | 1223 |
alternating components | 896 |
HOSTGUEST INCLUSION COMPLEXES | 906 |
transfer between the components? | 908 |
Introduction to Part III | 921 |
Structural principles in the classification of binary adducts | 926 |
Layered molecules with intramolecular donoracceptor | 959 |
Häufige Begriffe und Wortgruppen
Acta Cryst adduct analogous angle anion ANTCYB anthracene arrangement atoms benzene bond lengths carbonyl cation cation radical cell dimensions centrosymmetric chains charge transfer interactions Chem components conductivity coordination crystal structure crystalline crystallographic cyclophane diastereoisomer diffraction dimers disordered distances donor and acceptor donor-acceptor electron enthalpy examples formation Herbstein HgCl2 hydrogen bonds interplanar spacing intramolecular ionic ions isomorphous kJ/mol Krieger layers linked Matsunaga measurements mixed stack mixed-stack moieties molecular complexes molecular compounds molecules monoclinic naphthalene NAPTCB NC CN neutral oxygen pairs parameters perylene phase transition Phys picric acid planar planes PMDA polymorph proton Prout pyrene quinhydrone R/EB overlap radical salts range reported Reproduced room temperature S/cm Saito Section segregated stack shown similar space group spectra spectroscopy Staab stack axis stack structure studies Table TCNE TCNQ TCNQ moieties tetrads triclinic TTF][TCNQ unit cell values Wallwork